There is definitely a noticeable difference between pharmacy grade 70% and tech grade 100%, but I suspect that the difference between 99 and 100% is not something you can notice. Or, maybe they are the same except that 99% is probably labeled as such in an effort to err on the side of caution.
However........ I also suspect you really mean 90% and not 99% in which case, if you want maximum strength, then 100% is better than 90%.