Use the largest you can. You should at least double the expected voltage at the output. At the very minimum. I have seen boomboxes use 50v capacitors at the speakers. If your boombox consumes 80 watts, it is a fairly heavy hitter. I don't expect the capacitors to blow up but they might last longer. Power consumption is not a reliable indicator of output voltage. Much has to do with efficiency of the amps, effiency of the power supply, input voltage, quiescient / bias current of the devices, whether indicator lamps are lit, the number of features, thus circuits, etc.
When it comes to Film and polypropylene capacitors, I have heard audiophiles wanting to use 100 to 250 volt caps. The reason has to do with the physical size of the cap (higher voltage units are larger) and the resonance of the audio signal as it goes through the cap although I suspect the actual reason is not known. Probably through trial/error was it discovered and the consensus is to use high voltage caps for the crossovers.
You may be overthinking this Jovie. It's a boombox. Toss a couple of 4.7uf or 10uf bipolars in it and if the tweets aren't blown, I think you'll be very happy with the result.